removal efficiency of some biosorbents in removing of cadmium from aqueous solution

نویسندگان

ابراهیم سپهر

دانشیار گروه علوم خاک، دانشکدۀ کشاورزی، دانشگاه ارومیه امیر توسن

کارشناس ارشد علوم خاک، دانشکدۀ کشاورزی، دانشگاه ارومیه

چکیده

the application of organic sorbents for removing heavy metal from water, replacing expensive sorbents, is particularly appropriate for developing countries. to investigate the efficiency of some organic sorbents in removing of cd2+ from aqueous solution, an experiment was conducted with three organic sorbents (sunflower stalks, apple and grapevine pruning residues) and 11 initial concentration of cd2+ (0- 200 mg l-1) at three ph (4, 6, 8). the results showed that three organic sorbents have relatively high removal efficiency (re) for cadmium from aqueous solution, and re increased with increasing of ph but initial concentration of cadmium showed invers effect. the highest re was obtained at ph 8 and low initial concentration of cd (≤10 mg l-1) for all three organic sorbents. among sorption models (langmuir, temkin and freundlich), langmuir model was better fitted for experimental data (r2= 0.99). at ph8, maximum mono layer adsorption (qmax) of sunflower stalks, apple and grape pruning residues were obtained 8905, 8155 and 7895 mg kg-1, respectively. all sorption parameters (qmax, a, kf, kt, kl, n) of sunflower stalks was more than those of apple and grape pruning residues. therefore, sunflower stalks in comparison to apple and grape pruning residues, have a high efficiency in removing of cadmium from aqueous solution. the gibbs free energy of reaction (δgr) and separation factor of langmuir (rl) indicated that the sorption reaction of cd2+ by all three biosorbents are spontaneous and favorable.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

REMOVAL OF CADMIUM FROM AQUEOUS SOLUTION USING COBALTSILICATEPRECIPITATIONTUBE (CoSPT) ASADSORBENT

Cobalt silicate precipitation tube (CoSPT), prepared through ‘silica garden’ route was found to be a potential adsorbent for removal of cadmium from aqueous medium. Detail adsorption study of Cd(II) on CoSPT was investigated. Batch adsorption studies were carried out as a function of contact time, adsorbent dose, adsorbate concentration (50-300 mg L-1), temperature (298-323K). Cd(II) loading on...

متن کامل

Efficiency of Aptenia Cordifolia Mucilage in Removal of Anion Dyes from Aqueous Solution

Dye-containing wastewater is one of the main environmental challenges that can cause health issues. It is crucial to remove the dyes from wastewater before its discharge into the environment. This study aims to evaluate the efficiency of aptenia cordifolia mucilage in removal of anionic dyes from textile wastewater via coagulation and flocculation process. To this goal, the effect of different ...

متن کامل

evaluations of effective factors on efficiency zinc oxides nanoparticles in cadmium removal from aqueous solution

introduction: cadmium is a heavy metal with high toxicity and is best known as a carcinogen element. for protecting human health and environment it is necessary to remove excess cadmium from industrial wastewater before discharging it to surface and ground water. in this study the efficiency of zinc oxides nanoparticles in cadmium removal from aqueous solution was evaluated. methods: this is a ...

متن کامل

Evaluating the Fenton Process Efficiency in Removal of Reactive Red 2 from Aqueous Solution

Introduction: Dyes are visible materials and are considered as one of the hazardous components that make up industrial waste. Therefore it is removed from bodies of water, using various methods. In this regard, the Fenton oxidation process is one of the most effective ways to remove colored contaminants in aquatic environments, which has many applications today. Materials and Methods: In this...

متن کامل

Removal of Cadmium and Lead Ions from Aqueous Solution by Nanocrystalline Magnetite Through Mechanochemical Activation

In this study, the removal of cadmium and lead ions from aqueous solution by nanocrystalline magnetite was investigated. The nanocrystalline magnetite was synthesized by mechanochemical activation of hematite in a high energy planetary mill in argon atmosphere for 45 hours. The ability of the synthesized nanocrystalline magnetite for removal of Cd(II) and Pb(II) from aqueous solutions was studi...

متن کامل

Adsorption Efficiency of Iron Modified Carbons for Removal of Pb(II) Ions from Aqueous Solution

Abstract Introduction: The Lead causes severe damage to several systems of the body, especially to bony tissues. Until now, several low-cost biosorbents have been studied for removal of heavy metal ions from aqueous solutions. In the present study, carbonized pomegranate peels modified with Fe2+ and Fe3+ ions and then it was investigated for removal of Pb(II) ions from aqueous solution. ...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
محیط زیست طبیعی

جلد ۶۸، شماره ۴، صفحات ۵۸۳-۵۹۴

کلمات کلیدی
[ ' t h e a p p l i c a t i o n o f o r g a n i c s o r b e n t s f o r r e m o v i n g h e a v y m e t a l f r o m w a t e r ' , ' r e p l a c i n g e x p e n s i v e s o r b e n t s ' , ' i s p a r t i c u l a r l y a p p r o p r i a t e f o r d e v e l o p i n g c o u n t r i e s . t o i n v e s t i g a t e t h e e f f i c i e n c y o f s o m e o r g a n i c s o r b e n t s i n r e m o v i n g o f c d 2 + f r o m a q u e o u s s o l u t i o n ' , ' a n e x p e r i m e n t w a s c o n d u c t e d w i t h t h r e e o r g a n i c s o r b e n t s ( s u n f l o w e r s t a l k s ' , ' a p p l e a n d g r a p e v i n e p r u n i n g r e s i d u e s ) a n d 1 1 i n i t i a l c o n c e n t r a t i o n o f c d 2 + ( 0 ' , ' 2 0 0 m g l ' , ' 1 ) a t t h r e e p h ( 4 ' , 6 , ' 8 ) . t h e r e s u l t s s h o w e d t h a t t h r e e o r g a n i c s o r b e n t s h a v e r e l a t i v e l y h i g h r e m o v a l e f f i c i e n c y ( r e ) f o r c a d m i u m f r o m a q u e o u s s o l u t i o n ' , ' a n d r e i n c r e a s e d w i t h i n c r e a s i n g o f p h b u t i n i t i a l c o n c e n t r a t i o n o f c a d m i u m s h o w e d i n v e r s e f f e c t . t h e h i g h e s t r e w a s o b t a i n e d a t p h 8 a n d l o w i n i t i a l c o n c e n t r a t i o n o f c d ( 1 0 m g l ' , ' 1 ) f o r a l l t h r e e o r g a n i c s o r b e n t s . a m o n g s o r p t i o n m o d e l s ( l a n g m u i r ' , ' t e m k i n a n d f r e u n d l i c h ) ' , ' l a n g m u i r m o d e l w a s b e t t e r f i t t e d f o r e x p e r i m e n t a l d a t a ( r 2 = 0 . 9 9 ) . a t p h 8 ' , ' m a x i m u m m o n o l a y e r a d s o r p t i o n ( q m a x ) o f s u n f l o w e r s t a l k s ' , ' a p p l e a n d g r a p e p r u n i n g r e s i d u e s w e r e o b t a i n e d 8 9 0 5 ' , ' 8 1 5 5 a n d 7 8 9 5 m g k g ' , 1 , ' r e s p e c t i v e l y . a l l s o r p t i o n p a r a m e t e r s ( q m a x ' , ' a ' , ' k f ' , ' k t ' , ' k l ' , ' n ) o f s u n f l o w e r s t a l k s w a s m o r e t h a n t h o s e o f a p p l e a n d g r a p e p r u n i n g r e s i d u e s . t h e r e f o r e ' , ' s u n f l o w e r s t a l k s i n c o m p a r i s o n t o a p p l e a n d g r a p e p r u n i n g r e s i d u e s ' , ' h a v e a h i g h e f f i c i e n c y i n r e m o v i n g o f c a d m i u m f r o m a q u e o u s s o l u t i o n . t h e g i b b s f r e e e n e r g y o f r e a c t i o n ( δ g r ) a n d s e p a r a t i o n f a c t o r o f l a n g m u i r ( r l ) i n d i c a t e d t h a t t h e s o r p t i o n r e a c t i o n o f c d 2 + b y a l l t h r e e b i o s o r b e n t s a r e s p o n t a n e o u s a n d f a v o r a b l e . ' ]

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023